Quantitative determination in urine of hippuric acid and m- or p-methylhippuric acid, metabolites of toluene and m- or p-xylene

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Urinary excretion of hippuric acid and m- or p-methylhippuric acid in the urine of persons exposed to vapours of toluene and m- or p-xylene as a test of exposure.

Ogata, M., Tomokuni, K., and Takatsuka, Y. (1970). Brit. J. industr. Med., 27,43-50. Urinary excretion of hippuric acid and mor p-methylhippuric acid in the urine of persons exposed to vapours of toluene and mor p-xylene as a test of exposure. Twenty-three male volunteers were exposed in groups of four or five to toluene and mand p-xylene vapour for periods of 3 hours or of 7 hours with one bre...

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Thin-layer chromatography of hippuric and m-methylhippuric acid in urine after mixed exposure to toluene and xylene.

The separation of hippuric and m-methylhippuric acid as toluene and m-xylene metabolites present in urine of people exposed simultaneously to toluene and xylene is described. Chloroform was used for hippuric and m-methylhippuric acid extraction. Satisfactory separation of these metabolites was obtained on TLC plates covered with silica gels and developed in chloroform acetic acid-water (4:1:1);...

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Quantitative determination of hippuric and m-methylhippuric acids in urine by high-speed liquid chromatography.

High-speed liquid chromatography employing an ultraviolet photometric detector has been applied to the simultaneous determination of hippuric and m-methylhippuric acids in urine. Reversed-phase partition chromatography is carried out on a muBondapak C18 column with methanol-water as the eluent system. This method obviates the necessity for isolation or reaction of these acids before assay. The ...

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Absorption of m-xylene vapours through the respiratory tract and excretion of m-methylhippuric acid in urine.

Absorption of m-xylene and excretion of m-methylhippuric acid were investigated under controlled conditions in ten volunteers aged 17-33 years. They were exposed to m-xylene vapours at concentrations of 100, 300, and 600 mg/m3. It was found that m-xylene vapour retained in the lungs tended to decrease at the end of the exposure. An exposure test was devised, based upon the results obtained duri...

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Growth and Characterization of Urea Adduct with m-Nitrobenzoic Acid,m-Nitroaniline, and p-Xylene Mixtures

The urea adduct with the guests of m-nitrobenzoic acid, m-nitroaniline and p-xylene mixtures by adductive crystallization was successfully grown by slow evaporation method. The single crystals obtained were non-hygroscopic and good in size. The crystal structure of the grown crystal has been determined, and it belongs to the monoclinic system with centrosymmertic space group P21/c. Fourier tran...

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ژورنال

عنوان ژورنال: Occupational and Environmental Medicine

سال: 1969

ISSN: 1351-0711

DOI: 10.1136/oem.26.4.330